The arrangement of electron pairs around the central iodine atom in the molecule iodine tribromide (IBr3) dictates its electron-pair geometry. This geometry considers all electron pairs, both bonding and non-bonding (lone pairs), surrounding the central atom. In IBr3, the iodine atom is bonded to three bromine atoms and also possesses two lone pairs of electrons.
Understanding the spatial arrangement of electron pairs is crucial for predicting molecular shape and reactivity. The electron-pair geometry influences properties like bond angles and dipole moment, which, in turn, determine how a molecule interacts with other molecules. Historically, the prediction of these geometries relied on experimental techniques, but advancements in theoretical chemistry now allow accurate predictions using computational methods.